化学与材料科学学院

化学与材料科学学院

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倪祁健

作者:倪祁健     发布时间:2019-10-21 点击数:


         倪祁健博士,硕士生导师

         办公室:花津校区化学与材料科学学院礼勤楼1116

         实验室:花津校区化学与材料科学学院礼勤楼1123-1124

         Email:qijianni@ahnu.edu.cn

 


教育经历

  • 2004.09-2008.07安徽师范大学 理学学士(导师:罗时忠)

  • 2008.09-2011.07大连理工大学 工学硕士(导师:刘春)

  • 2011.09-2015.07德国亚琛工业大学 理学博士(导师:Dieter Enders)


工作经历

  • 2015.10-2017.10新加坡国立大学 博士后(合作导师:赵宇)

  • 2017.10 至今 安徽师范大学 化学与材料科学学院


主持项目

  • 2021.1-2023.12, 国家自然科学青年基金“不对称有机小分子催化/去芳构化策略构建苯并含氮杂环类化合物”(22001010),项目负责人

  • 2019.7-2021.6 安徽省自然科学青年基金“不对称脱羧环化构建中环含氮杂环化合物”(1908085QB55),项目负责人

  • 2018年安徽省平台引才资助经费,项目负责人

  • 安徽师范大学博士科研启动基金,项目负责人


研究领域

  • 不对称过渡金属催化

  • 有机小分子催化


课题组成员

  • 在读硕士生:

    18级(王旭阳、曾达、许磊)

    19级(朱智铭、许方方、范彦君)

    20级 (张莅蓉、姜旭华、秦唯)

  • 本科生:

    16级大学生创新实验团队(顾孟杰、荚瑞、沈月;唐伟、张莅蓉、张利沙)

    17级大学生创新训练项目(张旭)

    18级大学生创新训练项目(赵远,周欢)     


研究论文

独立工作后发表论文:

16)Xiaoxiao Song*,Lei Xu,Qijian Ni*.Highly diastereoselective synthesis of 3-methylenetetrahydropyrans by palladium c-atalyzed oxa-[4 + 2] cycloaddition of 2-alkenylbenzothiazoles,Org. Biomol. Chem.,2020,18, 6617-6621.link

15) Qijian Ni*, Xuyang Wang, Fangfang Xu, Xiaoyun Chen, Xiaoxiao Song*. Organocatalytic asymmetric [4+2] cyclization of 2-benzothiazolimines with azlactones: access to chiral benzothiazolopyrimidine derivatives,Chem. Commun.2020,56,3155-3158.link

14) Xiaoxiao Song*, Mengjie Gu, Xiaoyun Chen, Lei Xu,Qijian Ni*. Highly Stereoselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Epoxides and N-Benzothiazolimine,Asian J. Org. Chem.2019,8, 2180-2183.link

独立工作前发表论文:

13) Jiayu Liao,Qijian Ni, Yu Zhao*. Catalyst-Enabled Scaffold Diversity: Highly Chemo- and Stereoselective Synthesis of Tricyclic Ketals and Triarylmethanes,Org. Lett.2017,19, 4074-4077.

12) Tao Shu,Qijian Ni, Xiaoxiao Song, Kun Zhao, Tianyu Wu, Rakesh Puttreddy, Kari Rissanen, Dieter Enders*. Asymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction,Chem. Commun.2016,52, 2609-2611.

11) Qijian Ni, Jiawen Xiong, Xiaoxiao Song, Gerhard Raabe, Dieter Enders*. NHC-Catalyzed Activation of α,β-Unsaturated N-Acyltriazoles: An Easy Access to Dihydropyranones,Chem. Commun.2015,51, 14628-14631.

10) Qijian Ni, Jiawen Xiong, Xiaoxiao Song, Gerhard Raabe, Dieter Enders*. NHC-Catalyzed Enantioselective Annulation of Benzothiazolyl Ethyl Acetates with 2-Bromoenals,Synlett2015,26, 1465-1469.

9) Qijian Ni, Xiaoxiao Song, Jiawen Xiong, Gerhard Raabe, Dieter Enders*. Regio- and stereoselective synthesis of benzothiazolo-pyrimidinones via an NHC-catalyzed Mannich/lactamization domino reaction,Chem. Commun.2015,51, 1263-1266.

8) Lei Wang,Qijian Ni, Marcus Blümel, Tao Shu, Gerhard Raabe, Dieter Enders*. NHC-Catalyzed Asymmetric Synthesis of Functionalized Succinimides from Enals and α-Ketoamides,Chem. Eur. J.2015,21, 8033-8037.

7) Qijian Ni, Xiaoxiao Song, Gerhard Raabe, and Dieter Enders*. N-Heterocyclic Carbene-Catalyzed Enantioselective Annulation of Indolin-3-ones with Bromoenals,Chem. Asian J.2014,9, 1535-1538.

6) Xiaofei Zeng,Qijian Ni, Gerhard Raabe, Dieter Enders*. A Branched Domino Reaction: Asymmetric Organocatalytic Two-Component Four-Step Synthesis of Polyfunctionalized Cyclohexene Derivatives,Angew. Chem. Int. Ed.2013,52, 2977-2980.

5) Qijian Ni, Huan Zhang, André Grossmann, Charles C. J. Loh, Carina Merkens, Dieter Enders*. Asymmetric Synthesis of Pyrroloindolones by N-Heterocyclic Carbene Catalyzed [2+3] Annulation of α-Chloroaldehydes with Nitrovinylindoles,Angew. Chem. Int. Ed.2013,52, 13562-13566. (highlighted in SYNFACTS 2014, 212)

4) Chun Liu*,Qijian Ni, Fanying Bao, Jieshan Qiu. A simple and efficient protocol for the palladium-catalyzed ligand-free Suzuki reaction at room temperature in aqueous DMF,Green Chem.2011,13, 1260-1266.

3) Chun Liu*,Qijian Ni, Jieshan Qiu*. Very Fast, Ligand-Free and Aerobic Protocol for the Synthesis of 4-Aryl-Substituted Triphenylamine Derivatives,Eur. J. Org. Chem.2011, 3009-3015.

2) Chun Liu*,Qijian Ni, Pingping Hu, Jieshan Qiu. Oxygen-promoted PdCl2-catalyzed ligand-free Suzuki reaction in aqueous media,Org. Biomol. Chem.2011,9, 1054-1060.

1) 刘春*,倪祁健, 胡萍萍, 袁浩,金子林。水溶性亚胺配体/钯催化的室温Suzuki反应,催化学报2010,31, 1277-1280.


链接

新加坡国立大学赵宇教授

德国亚琛工业大学Dieter Enders教授

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