化学与材料科学学院

化学与材料科学学院

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贾卫国

作者: 贾卫国     发布时间:2020-11-06 点击数:

贾卫国 

E-mail: wgjiasy@ahnu.edu.cn

ORCID: https://orcid.org/0000-0001-7976-7543

实验室:理科大楼 832

 


教育背景:

学士: 化学教育 沈阳师范大学 化学与生命科学学院

硕士: 无机化学 辽宁大学 化学学院

博士: 无机化学 复旦大学 化学系

工作经历:

1. 2003 至今:安徽师范大学化学与材料科学学院,副教授 硕士生导师

2. 2010-2011年:博士后,阿卜杜拉国王科技大学

主持项目:

1. 金大环化合物的设计、合成及性能研究(国家自然科学基金,21102004/B02022012.1-2014.12.

2. 不对称钳形钌卡宾配合物的合成与性质研究 (教育部留学回国人员科研启动基金47) 2014.1-2016.12.

3. 金大环化合物的自组装及性质研究 (2011年高校省级科学研究项目重点项目KJ2011A1462011.1-2013.12.

4. 不对称钳形钌卡宾配合物的合成与性质研究(2016年度安徽高校自然科学研究项目KJ2016A8452016.1-2018.12.

5. 钳形钌配位化合物的合成及性质研究(2017年安徽省自然科学基金面上项目1708085MB442017.7-2019.6.

讲授课程:

1. 本科生:《无机化学》;《配位化学》;《化学实验》;《化学与健康》

2. 研究生:《高等无机化学》

研究领域:

1. 过渡金属配位化合物的合成、表征及其在有机化学中的应用

2. 金属有机化合物的合成及性质研究

1)半夹心钌有机金属配位化合物的精准合成及其在催化转移氢化反应中的应用研究;

2)多氮配位的钌基配位化合物精准合成及其在可见光催化转移氢化反应研究;

3)钳形苯基桥咪唑硫酮钯配位化合物精准合成及其在催化转移氢化反应研究。

 

 

 

 

 

课题组成员:

硕士研究生: 支雪婷(2018)李晓东(2019)谢晓蝶(2020

已毕业:戴源晨;李丹丹(2012);章慧(2013);凌硕 张台(2014);王之保 韩加勤(2015);程明霞(2016)高丽丽(2017

本科生:大学生创新创业训练计划:董庆广(2013);张海宁(2014);徐秋童(2015);支雪婷(2016);谭加红(2017);魏子翔(2017);周晓雨,朱高杰(2018);谢景佳,王晶晶(2019);曹玉昆,夏雪倩(2020

 

代表性论文:

1. Wei-Guo Jia, Li-Li Gao, Xue-Ting Zhi, Xiao-Dong Li, Zhi-Bao Wang, Ying Sun, Half-Sandwich Rhodium Complexes with Phenylene-based SCS Ligands: Synthesis, Characterization and Catalytic Activities for Transfer Hydrogenation of Ketones. Polyhedron, 2021, 195, 114978.

2. Wei-Guo Jia, Teng-Teng Du, Li-Li Gao, Jun Du, Synthesis, Characterization and Catalytic Activity of Half-sandwich Ruthenium Complexes with Pyridine/Phenylene Bridged NHC=E (NHC = N-heterocyclic carbene, E = S, Se) Ligands, Appl. Organomet. Chem., 2020, 34, e5651.

3. Wei-Guo Jia, Li-Li Gao, Zhi-Bao Wang, Jing-Jing Wang, En-Hong Sheng, and Ying-Feng Han*b,c, NHC-Palladium (II) Mononuclear and Binuclear Complexes Containing Phenylene-bridged Bis(thione) Ligands: Synthesis, Characterization and Catalytic Activities, Organometallics, 2020, 39, 1790-1798.

4. Wei-Guo Jia*, Zhi-Bao Wang, Xue-Ting Zhi, Half-sandwich Ruthenium Complexes with Schiff Base Ligands  Bearing a Hydroxyl Group: Preparation, Characterization and Catalytic Activities, Appl. Organomet. Chem., 2020, 34, e5289.

5. Wei-Guo Jia, Ming-Xia Cheng, Li-Li Gao, Siu Min Tan, Chao Wang, Xiaogang Liu, Richmond Lee, Ruthenium Bisoxazoline Complex as Photoredox Catalyst for Nitro Compound Reduction under Visible Light, Dalton Trans., 2019, 48, 9949-9953

6. Wei-Guo Jia, Li-Li Gao, Zhi-Bao Wang, Li-Ying Sun, and Ying-Feng Han, Synthesis, Characterization and Catalytic Activities of Palladium Complexes with Phenylene-bridged Bis(thione) Ligands, Organometallics, 2019, 38, 1946-1954

7. Li-Li Ma, Jia-Qin Han, Wei-Guo Jia*and Ying-Feng HanCoordination-driven self-assembly vs dynamic covalent chemistry: versatile methods for the synthesis of molecular metallarectangles, Beilstein J. Org. Chem. 2018, 14, 2027-2034.

8. Wei-Guo Jia, Shuo Ling, Hai-Ning Zhang, En-Hong Sheng and Richmond Lee, Half-sandwich Ruthenium Phenolate-Oxazoline Complexes: Experimental and Theoretical Studies in Catalytic Transfer Hydrogenation of Nitroarene, Organometallics, 2018, 37, 40-47.  

9. Wei-Guo Jia, Tai Zhang, Dong Xie, Qiu-Tong Xu, Shuo Ling and Qing Zhang, Half-sandwich Cycloruthenated Complexes from Aryloxazolines: Synthesis, Structures, and Catalytic activities, Dalton Trans., 2016, 45, 14230-14237.

10. Wei-Guo Jia, Hui Zhang, Tai Zhang, Dong Xie, Shuo Ling, En-Hong Sheng, Half-sandwich Ruthenium Complexes With Schiff Base Ligands: Syntheses, Characterization and Catalytic Activities for the Reduction of Nitroarenes, Organometallics, 2016, 35, 503-512.

11. Liyan Zhang, Lulu Rong, Guoli Hu, Suo Jin, Wei-Guo Jia, Ji Liu, Guozan Yuan, Six Zn(II) and Cd(II) coordination polymers assembled from a similar binuclear building unit: tunable structures and luminescence properties, Dalton Trans., 2015, 44, 6731-6739.

12. Wei-Guo Jia*, Dan-Dan Li, Yuan-Chen Dai, Hui Zhang, Li-Qin Yan, En-Hong Sheng, Yun Wei, Xiao-Long Mu and Kuo-Wei Huang Synthesis and characterization of bisoxazolines- and pybox-copper(II) complexes and their application in the coupling of α-carbonyls with functionalized amines Org. Biomol. Chem., 2014,12, 5509-5516

13. Ying Feng Han, Wei-Guo Jia, Yue-Jian Lin, Guo-Xin Jin, Extending Rectangular Metalorganic Frames to the Third Dimension: Discrete Organometallic Boxes for Reversible Trapping of Halocarbons Occuring with Conservation of the Lattice, Angew. Chem. Int. Ed., 2009, 48, 6234 –6238. 

14. Ying Feng Han, Wei-Guo Jia, Wei-Bin Yu, Guo-Xin Jin, Stepwise formation of organometallic macrocycles, prisms and boxes from Ir, Rh and Ru-based.half- sandwich units, Chem. Soc. Rev., 2009, 38, 3419-3434.

15. Wei-Guo Jia, Ying-Feng Han, Yue-Jian Lin, Lin-Hong Weng and Guo-Xin Jin, Stepwise Formation of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing 2,5-Diarylamino-1,4-Benzoquinone Derivatives.Organometallics, 2009, 28, 3459-3464.

16. Wei-Guo Jia, Ying-Feng Han, Guo-Xin Jin, Synthesis and characterization of binuclear half-sandwich iridium and rhodium carbene complexes containing 1,2-dichalcogenolato carborane or carbonato ligands, Organometallics, 2008, 27, 6035-6038.

17. Wei-Guo Jia, Yuan-Biao Huang, Yue-Jian Lin, Guo-Xin Jin, Syntheses and structures of half-sandwich iridium(III) and rhodium(III) complexes with organochalcogen (S, Se) ligands bearing N-methylimidazole and their use as catalysts for norbornene polymerization, Dalton Trans., 2008, 41, 5612-5620.

专利:

1. 贾卫国,李丹丹,孙影,盛恩宏:一种溴化铜试剂及其制备方法、α-胺基苯丙酮及其衍生物的合成方法中国发明专利:(授权公告号:CN 103848854 B;授权公告日:2016.6.01.

2. 贾卫国、戴源晨、孙影、盛恩宏:一种锌试剂及其制备方法、应用中国发明专利:(授权公告号:CN 103923111 B;授权公告日:2016.7.27.

3. 贾卫国,李丹丹,孙影,盛恩宏:苯甲酸酯类化合物的制备方法中国发明专利:(授权公告号:CN 104086427 B;授权公告日:2016.3.30.

4. 贾卫国,章慧,戴源晨:半夹心钌配位化合物及其制备方法和应用中国发明专利:(授权公告号:CN 104876969 B;授权公告日:2017.11.07.

5. 贾卫国,张台:一种半夹心环金属化钌配位化合物及其制备方法和应用中国发明专利:(授权公告号:CN 105153237 B;授权公告日:2019.5.14.

6. 贾卫国,凌硕,孙影:半夹心钌配合物及其制备方法、配体的制备方法以及硝基苯类化合物的还原方法中国发明专利:(授权公告号:CN 106046061 B;授权公告日:2019.3.26.

7. 贾卫国,王之保,孙影:含有羟基的半夹心钌配位化合物、制备方法和将硝基苯类化合物还原成苯胺类化合物的方法中国发明专利:((授权公告号:CN 106349295 B;授权公告日:2019.8.13.

8. 贾卫国,徐秋童,孙影:半夹心结构的钌配合物及其制备方法、将邻硝基苯乙醇类化合物还原为吲哚类化合物的方法中国发明专利:(授权公告号:CN 106905373 B;授权公告日:2019.3.26

9. 贾卫国,程明霞:钌(II)联噁唑啉吡啶化合物及其制备方法以及芳香硝基化合物的催化还原方法中国发明专利:(授权公告号:CN 108586540 B;授权公告日:2020.5.5.

 


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