贾卫国 

E-mail: wgjiasy@ahnu.edu.cn

ORCID: https://orcid.org/0000-0001-7976-7543

实验室：理科大楼 832、625

  博士毕业于复旦大学（2009），阿卜杜拉国王科技大学博士后（2010-2011），副教授，硕士生导师。主要承担《无机化学》、《高等无机化学》等本科生、研究生课程的教学任务。主要从事过渡金属配位化合物的合成与性质研究的研究工作。

主持项目:

1. 金大环化合物的设计、合成及性能研究（国家自然科学基金，21102004/B0202）2012.1-2014.12.

2. 不对称钳形钌卡宾配合物的合成与性质研究 (教育部留学回国人员科研启动基金47批) 2014.1-2016.12.

3. 金大环化合物的自组装及性质研究 （2011年高校省级科学研究项目重点项目KJ2011A146）2011.1-2013.12.

4. 不对称钳形钌卡宾配合物的合成与性质研究（2016年度安徽高校自然科学研究项目KJ2016A845）2016.1-2018.12.

5. 钳形钌配位化合物的合成及性质研究（2017年安徽省自然科学基金面上项目1708085MB44）2017.7-2019.6.

研究领域:

1. 过渡金属配位化合物的合成、表征及其在有机化学中的应用

2. 金属有机化合物的合成及性质研究

（1）半夹心钌有机金属配位化合物的精准合成及其在催化转移氢化反应中的应用研究；

（2）多氮配位的钌基配位化合物精准合成及其在可见光催化转移氢化反应研究；

（3）钳形苯基桥连咪唑硫酮钯配位化合物精准合成及其在催化转移氢化反应研究。

课题组成员:

硕士研究生： 王坤（2021）尹迪（2022）；李雪 （2023）；李琳（2024）

代表性论文:

1.  Wei-Guo Jia, Xue-Ting Zhi, Xiao-Dong Li, Jun-Peng Zhou, Rui Zhong, Haibo Yu, Richmond Lee*, Post-synthetic Modification of Half-Sandwich Ruthenium Complexes by Mechanochemical Synthesis. Inorg. Chem. 2021, 60, 4313-4321.

2. Wei-Guo Jia, Li-Li Gao, Xue-Ting Zhi, Xiao-Dong Li, Zhi-Bao Wang, Ying Sun, Half-Sandwich Rhodium Complexes with Phenylene-based SCS Ligands: Synthesis, Characterization and Catalytic Activities for Transfer Hydrogenation of Ketones. Polyhedron, 2021, 195, 114978.

3. Wei-Guo Jia, Teng-Teng Du, Li-Li Gao, Jun Du, Synthesis, Characterization and Catalytic Activity of Half-sandwich Ruthenium Complexes with Pyridine/Phenylene Bridged NHC=E (NHC = N-heterocyclic carbene, E = S, Se) Ligands, Appl. Organomet. Chem., 2020, 34, e5651.

4. Wei-Guo Jia, Li-Li Gao, Zhi-Bao Wang, Jing-Jing Wang, En-Hong Sheng, and Ying-Feng Han*^b,c, NHC-Palladium (II) Mononuclear and Binuclear Complexes Containing Phenylene-bridged Bis(thione) Ligands: Synthesis, Characterization and Catalytic Activities, Organometallics, 2020, 39, 1790-1798.

5. Wei-Guo Jia*, Zhi-Bao Wang, Xue-Ting Zhi, Half-sandwich Ruthenium Complexes with Schiff Base Ligands  Bearing a Hydroxyl Group: Preparation, Characterization and Catalytic Activities, Appl. Organomet. Chem., 2020, 34, e5289.

6. Wei-Guo Jia, Ming-Xia Cheng, Li-Li Gao, Siu Min Tan, Chao Wang, Xiaogang Liu, Richmond Lee, Ruthenium Bisoxazoline Complex as Photoredox Catalyst for Nitro Compound Reduction under Visible Light, Dalton Trans., 2019, 48, 9949-9953

7. Wei-Guo Jia, Li-Li Gao, Zhi-Bao Wang, Li-Ying Sun, and Ying-Feng Han, Synthesis, Characterization and Catalytic Activities of Palladium Complexes with Phenylene-bridged Bis(thione) Ligands, Organometallics, 2019, 38, 1946-1954

8. Li-Li Ma, Jia-Qin Han, Wei-Guo Jia*and Ying-Feng Han，Coordination-driven self-assembly vs dynamic covalent chemistry: versatile methods for the synthesis of molecular metallarectangles, Beilstein J. Org. Chem. 2018, 14, 2027-2034.

9. Wei-Guo Jia, Shuo Ling, Hai-Ning Zhang, En-Hong Sheng and Richmond Lee, Half-sandwich Ruthenium Phenolate-Oxazoline Complexes: Experimental and Theoretical Studies in Catalytic Transfer Hydrogenation of Nitroarene, Organometallics, 2018, 37, 40-47.  

10. Wei-Guo Jia, Tai Zhang, Dong Xie, Qiu-Tong Xu, Shuo Ling and Qing Zhang, Half-sandwich Cycloruthenated Complexes from Aryloxazolines: Synthesis, Structures, and Catalytic activities, Dalton Trans., 2016, 45, 14230-14237.

11. Wei-Guo Jia, Hui Zhang, Tai Zhang, Dong Xie, Shuo Ling, En-Hong Sheng, Half-sandwich Ruthenium Complexes With Schiff Base Ligands: Syntheses, Characterization and Catalytic Activities for the Reduction of Nitroarenes, Organometallics, 2016, 35, 503-512.

12. Liyan Zhang, Lulu Rong, Guoli Hu, Suo Jin, Wei-Guo Jia, Ji Liu, Guozan Yuan, Six Zn(II) and Cd(II) coordination polymers assembled from a similar binuclear building unit: tunable structures and luminescence properties, Dalton Trans., 2015, 44, 6731-6739.

13. Wei-Guo Jia*, Dan-Dan Li, Yuan-Chen Dai, Hui Zhang, Li-Qin Yan, En-Hong Sheng, Yun Wei, Xiao-Long Mu and Kuo-Wei Huang Synthesis and characterization of bisoxazolines- and pybox-copper(II) complexes and their application in the coupling of α-carbonyls with functionalized amines Org. Biomol. Chem., 2014,12, 5509-5516

14. Ying Feng Han, Wei-Guo Jia, Yue-Jian Lin, Guo-Xin Jin, Extending Rectangular Metalorganic Frames to the Third Dimension: Discrete Organometallic Boxes for Reversible Trapping of Halocarbons Occuring with Conservation of the Lattice, Angew. Chem. Int. Ed., 2009, 48, 6234 –6238. 

15. Ying Feng Han, Wei-Guo Jia, Wei-Bin Yu, Guo-Xin Jin, Stepwise formation of organometallic macrocycles, prisms and boxes from Ir, Rh and Ru-based.half- sandwich units, Chem. Soc. Rev., 2009, 38, 3419-3434.

16. Wei-Guo Jia, Ying-Feng Han, Yue-Jian Lin, Lin-Hong Weng and Guo-Xin Jin, Stepwise Formation of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing 2,5-Diarylamino-1,4-Benzoquinone Derivatives.Organometallics, 2009, 28, 3459-3464.

17. Wei-Guo Jia, Ying-Feng Han, Guo-Xin Jin, Synthesis and characterization of binuclear half-sandwich iridium and rhodium carbene complexes containing 1,2-dichalcogenolato carborane or carbonato ligands, Organometallics, 2008, 27, 6035-6038.

18. Wei-Guo Jia, Yuan-Biao Huang, Yue-Jian Lin, Guo-Xin Jin, Syntheses and structures of half-sandwich iridium(III) and rhodium(III) complexes with organochalcogen (S, Se) ligands bearing N-methylimidazole and their use as catalysts for norbornene polymerization, Dalton Trans., 2008, 41, 5612-5620.

专利：

1. 贾卫国，李丹丹，孙影，盛恩宏：“一种溴化铜试剂及其制备方法、α-胺基苯丙酮及其衍生物的合成方法” 中国发明专利：（授权公告号：CN 103848854 B；授权公告日：2016.6.01）.

2. 贾卫国、戴源晨、孙影、盛恩宏：“一种锌试剂及其制备方法、应用”中国发明专利：（授权公告号：CN 103923111 B；授权公告日：2016.7.27）.

3. 贾卫国，李丹丹，孙影，盛恩宏：“苯甲酸酯类化合物的制备方法”中国发明专利：（授权公告号：CN 104086427 B；授权公告日：2016.3.30）.

4. 贾卫国，章慧，戴源晨：“半夹心钌配位化合物及其制备方法和应用”中国发明专利：（授权公告号：CN 104876969 B；授权公告日：2017.11.07）.

5. 贾卫国，张台：“一种半夹心环金属化钌配位化合物及其制备方法和应用”中国发明专利：（授权公告号：CN 105153237 B；授权公告日：2019.5.14）.

6. 贾卫国，凌硕，孙影：“半夹心钌配合物及其制备方法、配体的制备方法以及硝基苯类化合物的还原方法”中国发明专利：（授权公告号：CN 106046061 B；授权公告日：2019.3.26）.

7. 贾卫国，王之保，孙影：“含有羟基的半夹心钌配位化合物、制备方法和将硝基苯类化合物还原成苯胺类化合物的方法”中国发明专利：（（授权公告号：CN 106349295 B；授权公告日：2019.8.13）.

8. 贾卫国，徐秋童，孙影：“半夹心结构的钌配合物及其制备方法、将邻硝基苯乙醇类化合物还原为吲哚类化合物的方法”中国发明专利：（授权公告号：CN 106905373 B；授权公告日：2019.3.26

9. 贾卫国，程明霞：“钌（II）联噁唑啉吡啶化合物及其制备方法以及芳香硝基化合物的催化还原方法”中国发明专利：（授权公告号：CN 108586540 B；授权公告日：2020.5.5）.