代胜瑜教授
个人信息
姓名: 代胜瑜
出生年月： 1990年2月
性别: 男
地址: 安徽省芜湖市安徽师范大学花津校区五号楼422
Researcher ID： http://orcid.org/0000-0003-4110-7691
课题组网站：https://www.x-mol.com/groups/dai_shengyu
教育：
09/2012-11/2016 硕博连读，高分子物理与化学，中国科学技术大学
09/2008-06/2012 本科，化学，安徽师范大学
研究经历：
12/2016 – 08/2018 博士后研究员，中国科学技术大学。
09/2018 – 10/2023 副教授，课题组长，安徽大学。
11/2023 – 至今 教授，课题组长，安徽师范大学
学术兼职：
1，Current Organic Chemistry (Impact Factor: 2.193) Executive Guest Editor
2,《合成化学》（中文科技核心收录）编辑部青年编委
3，Frontiers in Chemistry (Impact Factor: 5.545), Associate Editor.
4，Polymers (Impact Factor: 4.967), Executive Guest Editor.
5，Polymer International (Impact Factor: 3.213), Chief Guest Editor.
6, 《塑料工业》（北大核心），编辑，常务理事
研究方向：
课题组的研究主要是关于解决高分子材料制备与应用中存在的重要问题，解决这类问题需要通过先进的催化方法控制分子微观结构和纳米颗粒结构，同时要求其对极性官能团具有容忍性。从方法上讲，这包括催化机理的基础研究、目标导向性新催化剂的设计和新制备工艺的开发以及目标产品的分子和纳米结构，材料的性能以及与环境的相互作用的研究。目前课题组研究重点是单一乙烯原料制备不同品种高性能聚烯烃材料。目前已发表一作及通讯同行评审文章71篇，中科院分区一区16篇，其中8篇为ESI高被引文章，引用次数超过3200次，H因子为30 (Web of Science).
主持项目
纵向课题
1, 2017-2018 “系统研究二亚胺镍位阻变化对烯烃聚合和共聚的影响” 博士后面上基金，二等，5万元，项目编号：2017M612077。
2, 2017-2018 “不同芳杂环大位阻二亚胺钯镍催化剂在烯烃聚合和共聚中的应用”中国科学技术大学青年创新基金，15万元，项目编号：WK2060200024。
3, 2018-01-2020-12 “官能团化超高分子量聚烯烃材料的制备”国家自然科学基金青年科学基金，25 万元。项目编号：51703215。
4, 2021-01-2023-12 “单一乙烯原料精准合成多种高性能聚烯烃材料”安徽省优秀青年基金，20万元，项目编号：2108085Y06。
横向课题和技术服务
1, 2022-08-2024-08 聚烯烃基高分子纳米农药，江苏省科技副总项目, 江苏省科技厅和办公厅，50 万元。
2，202305-202307 “中海油东海部分油样中烃类和芳烃类化学物质结构与含量分析服务”洛阳智达石化工程有限公司，10万元。
3，202305-202311“聚烯烃弹性体茂金属催化剂的结构和合成工艺反演分析服务”洛阳智达石化工程有限公司，15万元。
开放课题
1, 2020-01 -2020-12 “生物质功能化聚烯的制备与应用”绿色高分子材料安徽省重点实验室2020年开放课题，2.5万元。
2, 2022-01-2022-12 “过渡金属催化的乙烯聚合制备聚烯烃热塑性弹性体” 安徽省教育厅洁净能源材料与催化物质转化化学重点实验室开放基金，2万元，项目编号：LCECSC-01。
3, 2022-09-2023-08 “单一乙烯原料制备聚乙烯热塑性弹性体材料”安徽师范大学分子基材料省级重点实验室开放基金，2万元
4, 202210-202410 “乙烯单一原料制备超支化聚乙烯基础油” 江苏省绿色催化材料与技术重点实验室开放项目，3万，项目编号：KF2202。
· 主要荣誉：
2023 爱思唯尔冯新德Polymer期刊最佳文章提名奖
2022 江苏省科技副总项目
2022 USERN (Universal Scientific Education and Research Network) 提名奖https://usern.tums.ac.ir/User/CV/daishengyuustc#
2021 合成化学杂志优秀编辑
2021 国际先进材料协会 "IAAM” Young Scientist Medal
2021 第七届中国聚烯烃大会 烯旺之星二等奖
2017 首届中国科学技术大学优秀博士论文提名奖（4%）
2016 研究生求是奖学金
2016 聚烯烃和润滑油专项奖学金
2015 博士生国家奖学金
2015 远东奖学金
2009 本科生朱敬文奖学金
主要发表文章：
在安徽大学
[78] Weiqing Lu, Beihang Ding, Wenping Zou, Shengyu Dai* Direct Synthesis of Polyethylene Thermoplastic Elastomers with High Molecular Weight and Excellent Elastic Recovery Via A Hybrid Steric Bulky Strategy. Eur. Polym. J. 2023, 201, 12577.
[77] Beihang Ding, Shengyu Dai* Palladium-Catalyzed Synthesis of Hyperbranched Polar Functionalized Polyethylene with High Density Hydrophilic Groups. ACS Applied Polymer Materials 2023, 5, 9536-9542.
[76] Xinyue Wu, Wenping Zou, Shengyu Dai* Functionalized Semicrystalline Polyethylene with Polar Groups at Branch End Enabled by Bulky Cationic Palladium Catalysts. J. Polym. Sci. 2023, DOI: 10.1002/pol.20230546.
[75] Wenbin Yuan, Weimin Li*, Shengyu Dai* Preparation of Polyethylene Thermoplastic Elastomers Using CS-Symmetric Nickel Catalysts in Ethylene Polymerization. Polymer, 2023, 285, 126322.
[74] Chuangao Zhu, Beihang Ding, Shengyu Dai* Synthesis of Branched Polyethylene Waxes Using Benzocycloalkyl Pyridine-Imine Ni(II) Catalysts with Dibenzosuberyl Group. J. Organomet. Chem., 2023, 1000, 122852.
[73] Zhou Lu, You Ge, Shengyu Dai* A Flexible Axial Shielding Strategy for Improving Ethylene (Co)polymerization with 8-Cycloalkylnaphthyl α-Diimine Catalysts. Inorg. Chem. 2023, 62, 14888-14895.
[72] Hua Wang, Zhou Lu*, Shengyu Dai* Synthesis of Hyperbranched Polyethylene and Carboxylate Functionalized Polyethylene Using Bis(benzocyclopentyl) α-Diimine Pd(II) Catalysts with Axial Substituent-Constrained Strategy. Eur. Polym. J. 2023, 193, 112247.
[71] Qi Cai, Fei Fang, Jiangang Gao*, Hui Wang*, Shengyu Dai* Preparation of Branched Oligoethylene and Polar Functionalized Oligoethylene Using Unsymmetrical Arylamine Based Cationic Ni(II) and Pd(II) Iminopyridyl Catalysts. Eur. Polym. J. 2023, 193, 112094.
[70] Zhengpeng Yan, Wenping Zou, Shengyu Dai* Unexpected o-Aryl tBu Group Effect on Suppression of Chain Transfer in Pyridine-Imine Ni(II) and Pd(II) Catalyzed Ethylene (Co)Polymerization. Polym. Chem., 2023, 14, 2107–2116.
[69] Hui Wang, Weiqing Lu, Huiqin Bi, Shengyu Dai* Dibenzosuberyl Substituents Suppressing Chain Transfer in Bis(imino)pyridyl Iron(II) Catalyzed Ethylene Polymerization. Polymer, 2023, 273, 125868.
[68] Beihang Ding, Lihang Jiang, Xiaohui Kang, Shengyu Dai* Enhancing Suppression of Chain Transfer via Catalyst Structural Evolution in Ethylene (Co)Polymerization. Chinese Journal of Chemistry, 2023, 41, 1509—1516. (Back cover)
[67] Hui Wang, Weiqing Lu, Mingmin Zou, Shengyu Dai* Direct Synthesis of Polyethylene Thermoplastic Elastomers Using Hybrid Bulky Acenaphthene-Based α‑Diimine Ni(II) Catalysts. Molecules 2023, 28, 2196161.
[66] Huayin Sun, Huijun Fan, Chuangao Zhua, Wenping Zou*, Shengyu Dai* Direct Synthesis of Partially Chain-straightened Propylene Oligomers and P-MA Co-oligomers Using Axially Flexible Shielded Iminopyridyl Palladium Complexes. Polymers 2023, 15, 111. (Invited Contributions)
[65] Huijun Fan†, Guanru Chang†, Hui Wang*, Shengyu Dai* Second Coordination Sphere Effect of Benzothiophene Groups Enhances Chain Transfer in Ethylene (Co)Oligomerization. New J. Chem., 2023, 47, 2488 - 2494.
[64] Zhou Lu†, Xiaowei Xu†, Yi Luo*, Shengbao He, Weigang Fan*, Shengyu Dai* The Unexpected Effect of Catalyst’s Structural Symmetry on Branching Microstructure of Polyethylene in Late Transition Metal Polymerization Catalysis. ACS Catal. 2023, 13, 725–734.
[63] Zhengpeng Yan, Guanru Chang, Wenping Zou, Gen Luo*, Shengyu Dai* Synthesis of Lightly Branched Ultrahigh-Molecular-Weight Polyethylene Using Cationic Benzocyclohexyl Nickel Catalysts. Polym. Chem., 2023, 14, 183-190.
[62] Weiqing Lu, Weigang Fan*, Shengyu Dai* A Rigid–Flexible Double-Layer Steric Strategy Promoting Ethylene Polymerization and Copolymerization in Alkane Solvents. Inorg. Chem. Front. 2023, 10, 108-117. (Highlighted by the Journal in Wechat and Twitter)
[61] Xinyue Wu†, Guoyong Xu†, Weiqing Lu, Zhong-Yuan Li*, Shengyu Dai* Ethylene (Co)oligomerization in Alkane Solvents Facilitated by Rigid-Flexible Double-Layer Steric Strategy. Eur. Polym. J. 2022, 169, 111459. (Accept directly without modifications)
[60] Jianhai Chen†, Zhengpeng Yan†, Zhong-Yuan Li, Shengyu Dai*, Direct Synthesis of Chain-End Toluene Functionalized Hyperbranched Ethylene Oligomers. Polymers 2022, 14, 3049. (Invited feature article with free APC)
[59] Yudan Liao†, Qi Cai†, Shengyu Dai* Synthesis of High Molecular Weight Polyethylene and E-MA Copolymers Using Iminopyridine Ni(II) and Pd(II) Complexes Containing a Flexible Backbone and Rigid Axial Substituents. Chin. J. Polym. Sci. 2023, 41, 233-239.
[58] Beihang Ding†, Guanru Chang†, Zhengpeng Yan, Shengyu Dai* Ethylene (Co)oligomerization Using Iminopyridyl Ni(II) and Pd(II) Complexes Bearing Benzocycloalkyl Moieties to Access Hyperbranched Ethylene Oligomers and Ethylene-MA Co-oligomers. Front. Chem. 2022, 10, 961426. (Invited Contributions)
[57] You Ge†, Zhou Lu†, Shengyu Dai* Flexible Axial Shielding Strategy for the Synthesis of High-Molecular-Weight Polyethylene and Polar Functionalized Polyethylene with Pyridine-imine Ni(II) and Pd(II) Complexes. Organometallics 2022, 41, 2042-2049. (Highlighted by ACS in Wechat)
[56] Huijun Fan†, Yudan Liao†, Shengyu Dai* Propylene Polymerization and Copolymerization with Polar Monomers Facilitated by Flexible Cycloalkyl Substituents in α-Diimine Systems. Polymer, 2022, 254, 125076.
[55] Zhou Lu†, Yudan Liao†, Weigang Fan*, Shengyu Dai* Efficient Suppression of Chain Transfer Reaction in Ethylene Coordination Polymerization with Dibenzosuberyl Substituents. Polym. Chem., 2022, 13, 4090–4099. (Selected as Front Cover)
[54] Weiqing Lu, Yudan Liao, Shengyu Dai* Facile Access to Ultra-Highly Branched Polyethylenes Using Hybrid “Sandwich” Ni(II) and Pd(II) Catalysts. J. Catal. 2022, 411, 54-61.
[53] You Ge†, Qi Cai†, Yuyin Wang, Jiangang Gao*, Yue Chi*, Shengyu Dai* Synthesis of High-Molecular-Weight Branched Polyethylene Using a Hybrid “Sandwich” Pyridine-Imine Ni(II) Catalyst. Front. Chem. 2022, 10, 886888. (Invited Contributions)
[52] Huijun Fan†, Guoyong Xu†, Hui Wang, Shengyu Dai* Direct Synthesis of Hyperbranched Ethylene Oligomers and Ethylene-MA Co-oligomers Using Iminopyridyl Systems with Weak Neighboring Group Interactions. J. Polym. Sci. 2022, 60, 1944–1953. (Front Cover; Highlighted by J. Polym. Sci. in Tweet; Highlighted by Wiley Advanced Science News, ESI Highly Cited Paper)
[51] Weiqing Lu, Hui Wang, Weigang Fan*, Shengyu Dai* Exploring the Relationship Between Polyethylene Microstructure and Spatial Structure of α-Diimine Pd(II) Catalysts via A Hybrid Steric Strategy. Inorg. Chem. 2022, 61, 6799–6806. (Highlighted by the Journal in Tweet)
[50] Zhengpeng Yan†, Huiqin Bi†, Beihang Ding, Hui Wang*, Guoyong Xu*, Shengyu Dai* A Rigid-Flexible Double-Layer Steric Strategy for Ethylene (Co)oligomerization with Pyridine-imine Ni(II) and Pd(II) Complexes. New J. Chem. 2022, 46, 8669 – 8678. (ESI Highly Cited Paper)
[49] Zhengpeng Yan†, Guoyong Xu†, Hui Wang, Shengyu Dai* Synthesis of Thermoplastic Polyethylene Elastomers and Ethylene-Methyl Acrylate Copolymers Using Methylene-Bridged Binuclear Bulky Dibenzhydryl α-Diimine Ni(II) and Pd(II) Catalysts. Eur. Polym. J. 2022, 168, 111105.
[48] Hui Wang, Gaokun Duan, Huijun Fan, Shengyu Dai* Second Coordination Sphere Effect of Benzothiophene Substituents on Chain Transfer and Chain Walking in Ethylene Insertion Polymerization. Polymer 2022, 245, 24707.
[47] Zhou Lu†, Guanru Chang†, Hui Wang, Kun Jing, Shengyu Dai* A Dual Steric Enhancement Strategy in α-Diimine Nickel and Palladium Catalysts for Ethylene Polymerization and Copolymerization. Organometallics 2022, 41, 124–132.
[46] Huijun Fan†, Guanru Chang†, Huiqin Bi, Xu Gui, Hui Wang*, Guoyong Xu*, Shengyu Dai* Facile Synthesis of Hyperbranched Ethylene Oligomers and Ethylene-Methyl Acrylate Co-oligomers with Different Microscopic Chain Architectures. ACS Polymers Au, 2022, 2, 88–96. (Invited Contributions)
[45] Weiqing Lu†, Guoyong Xu†, Guanru Chang*, Hui Wang*, Shengyu Dai* Synthesis of Highly Branched Polyethylene and Ethylene-MA Copolymers Using Hybrid Bulky α-Diimine Pd(II) Catalysts. J. Organomet. Chem., 2021, 953, 122118.
[44] Lihua Guo*, Xueyan Hu, Weiqing Lu, Guoyong Xu, Qin Liu, Shengyu Dai* Investigations of Ligand Backbone Effects on Bulky Diarylmethyl-based Nickel(II) and Palladium(II) Catalyzed Ethylene Polymerization and Copolymerization. J. Organomet. Chem., 2021, 952, 122046.
[43] Zhou Lu†, Hui Wang†, Shuaikang Li, Shengyu Dai* Direct Synthesis of Various Polar Functionalized Polypropylene with Tunable Molecular Weights and High Incorporation Ratios. Polym. Chem., 2021, 12, 5495–5504.
[42] You Ge, Shuaikang Li, Hui Wang*, Shengyu Dai* Synthesis of Branched Polyethylene and Ethylene-MA Copolymers Using Unsymmetrical Iminopyridyl Nickel and Palladium Complexes. Organometallics 2021, 40, 3033-3041.
[41] Zijuan Hai, Zhou Lu, Shuaikang Li, Zhong-Yan Cao*, Shengyu Dai* Synergistic Effect of Rigid and Flexible Substituents in Insertion Polymerization with a-Diimine Nickel and Palladium Catalysts. Polym. Chem., 2021, 12, 4643 – 4653.
[40] Weiqing Lu, Shengyu Dai* Neutral Unsymmetrical Coordinated Cyclophane Catalysts for Olefin Polymerization. Chin. J. Synth. Chem. 2021, 29, 902-903. (Invited Contributions)
[39] Zhengpeng Yan, Shuaikang Li, Shengyu Dai* Synthesis and Characterization of Hyperbranched Polar Functionalized Olefin Oligomers. Chin. J. Synth. Chem. 2021, 29, 1033-1044. (Invited Contributions)
[38] Shengyu Dai*, Gen Li, Weiqing Lu, Yudan Liao*, Weigang Fan* Suppression of Chain Transfer via Restricted Rotation Effect of Dibenzosuberyl Substituents in Polymerization Catalysis. Polym. Chem., 2021, 12, 3240–3249. (Front Cover)
[37] You Ge, Shuaikang Li, Weigang Fan*, Shengyu Dai* Flexible “Sandwich” (8 Alkylnaphthyl α Diimine) Catalysts in Insertion Polymerization. Inorg. Chem. 2021, 60, 5673−5681.
[36] Shuaikang Li†, Zhou Lu†, Weigang Fan*, Shengyu Dai* Efficient Incorporation of Polar Comonomer for Direct Synthesis of Hyperbranched Polar Functional Ethylene Oligomers. New J. Chem., 2021, 45, 4024 - 4031.
[35] Shuaikang Li, Yihua Zhao, Shengyu Dai* Synthesis of Polyethylene Thermoplastic Elastomer by Using Robust α-Diimine Ni(II) Catalysts with Abundant tBu Substituents. J. Polym. Sci., 2021, 59, 638–645.
[34] Yihua Zhao†, Shuaikang Li†, Weigang Fan*, Shengyu Dai* Reversion of the Chain Walking Ability of α-Diimine Nickel and Palladium Catalysts with Bulky Diarylmethyl Substituents. J. Organomet. Chem., 2021, 932, 121649.
[33] Chaoqun Wang,# Xiaohui Kang,# Shengyu Dai,# (共一) Fengchao Cui, Yunqi Li, Hongliang Mu, Stefan Mecking,* and Zhongbao Jian* Efficient Suppression of Chain Transfer and Branching via Cs-Type Shielding in a Neutral Ni(II) Catalyst. Angew. Chem. Int. Ed. 2021, 60, 4018 –4022.
[32] Hongwei Peng#, Shuaikang Li#, Gen Li, Shengyu Dai*, Mingjun Ji, Zhe Liu, Lihua Guo*, Rotation-Restricted Strategy to Synthesize High Molecular Weight Polyethylene Using Iminopyridyl Nickel and Palladium Catalyst. Appl. Organomet. Chem., 2021, 35, e6140.
[31] Shuaikang Li, Shengyu Dai* Highly Efficient Incorporation of Polar Comonomers in Copolymerizations with Ethylene Using Iminopyridyl Palladium System. J. Catal. 2021, 393, 51–59.
[30] Shuaikang Li, Shengyu Dai* 8-Arylnaphthyl Substituent Retarding Chain Transfer in Insertion Polymerization with Unsymmetrical α-Diimine Systems. Polym. Chem. 2020, 11, 7199-7206.
[29] Shengyu Dai, Changle Chen*. A Self-Supporting Strategy for Gas-Phase and Slurry-Phase Ethylene Polymerization using Late-Transition-Metal Catalysts. Angew. Chem. Int. Ed., 2020, 59, 14884–14890. Collections: Polymer Chemistry.
[28] Shengyu Dai*, Shuaikang Li, Guoyong Xu, Changle Chen* Direct Synthesis of Polar Functionalized Polyethylene Thermoplastic Elastomer. Macromolecules 2020, 53, 2539−2546.
[27] Shuaikang Li, Guoyong Xu, Shengyu Dai* A remote nonconjugated electron effect in insertion polymerization with α-diimine nickel and palladium species. Polym. Chem., 2020, 11, 2692–2699. Polymer Chemistry Most Popular 2020.
[26] Shengyu Dai*, Shuaikang Li, Guoyong Xu, Cheng Wu, Yudan Liao*, Lihua Guo* Flexible Cycloalkyl Substituents in Insertion Polymerization with α-Diimine Nickel and Palladium Species. Polym. Chem. 2020, 11, 1393 – 1400. Polymer Chemistry Most Popular 2020.
[25] Gen Li, Guoyong Xu, You Ge, Shengyu Dai* Synthesis of Fluorinated Polyethylene of Different Topologies via Insertion Polymerization with Semifluorinated Acrylates. Poly. Chem. 2020, 11, 6335–6342.
[24] Shengyu Dai*, Shuaikang Li. Effect of aryl orientation on olefin polymerization in iminopyridyl catalytic system. Polymer 2020, 200, 122607.
[23] Gen Li, You Ge, Guoyong Xu*, Shengyu Dai* The electronic effects on unsymmetrical Bis(imino)pyridyl iron(ii) catalyzed ethylene polymerization. J. Organomet. Chem., 2020, 923, 121457.
[22] Yanfeng Gong, Shuaikang Li, Chen Tan, Wenyu Kong, Shaojie Zhang*, Binyuan Liu*, Shengyu Dai* π–π Interaction Effect in Insertion Polymerization with α-Diimine Palladium Systems. J. Catal. 2019, 378, 184-191.
[21] Lihua Guo, Wenting Sun, Shuaikang Li, Guoyong Xu, Shengyu Dai* Bulky yet flexible substituents in insertion polymerization with α-diimine nickel and palladium systems. Polym. Chem. 2019, 10, 4866–4871.
[20] Lihua Guo, Shuaikang Li, Mingjun Ji, Wenting Sun, Wenjing Liu, Gen Li, Jingwen Zhang, Zhe Liu, Shengyu Dai* Monoligated vs Bisligated Effect in Iminopyridyl Nickel Catalyzed Ethylene Polymerization. Organometallics 2019, 38, 2800−2806.
[19] Yanfeng Gong, Shuaikang Li, Qi Gong, Shaojie Zhang*, Binyuan Liu*, Shengyu Dai* Systematic Investigations of Ligand Steric Effects on α‑Diimine Nickel Catalyzed Olefin Polymerization and Copolymerization. Organometallics 2019, 38, 2919−2926.
[18] Lihua Guo*, Wenjing Liu, Kun,Li, Mengmeng,Sun, Wenting Sun, Liping Zhao, Guorun Jiang, Hongwei Peng, Zhe Liu*, Shengyu Dai*. Synthesis of functional and hyperbranched ethylene oligomers using unsymmetrical α-diimine palladium catalysts. Eur. Polym. J. 2019, 115, 185-192.
[17] Lihua Guo, Kunbo Lian, Wenyu Kong, Shuai Xu, Guorun Jiang, Shengyu Dai*. Synthesis of Various Branched Ultra-High-Molecular-Weight Polyethylenes Using Sterically Hindered Acenaphthene-Based α-Diimine Ni(II) Catalysts. Organometallics 2018, 37, 2442-2449.
[16] Lihua Guo*, Yanlan Liu, Kunbo Lian, Wenting Sun, Huaxia Zhu, Zhe Liu*, Xiaoyu Chen, Shengyu Dai*. The Backbone Electronic Effects on Bis(imino)pyridyl Iron(II) Catalyzed Ethylene Polymerization. Eur. J. Inorg. Chem. 2018, 4887-4892.
[15] Lihua Guo*, Wenyu Kong, Yanjian Xu, Yuliang Yang, Rui Ma, Li Cong, Shengyu Dai*, Zhe Liu*. Large-scale synthesis of novel sterically hindered acenaphthene-based α-diimine ligands and their application in coordination chemistry. J. Organomet. Chem., 2018, 859, 58-67.
在中国科学技术大学
[14] Shengyu Dai, Changle Chen*. Palladium-Catalyzed Direct Synthesis of Various Branched, Carboxylic-Acid-Functionalized Polyolefins: Characterization, Derivatization and Properties. Macromolecules 2018, 51, 6818–6824. Monthly most read article in 2018/09. ESI Highly Cited Paper.
[13] Yinna Na,# Shengyu Dai (co-first),# Changle Chen*. Direct Synthesis of Polar-Functionalized Linear Low-Density Polyethylene (LLDPE) and Low-Density Polyethylene (LDPE). Macromolecules 2018, 51, 4040-4048. Monthly most read article in 2018/06. ESI Highly Cited Paper.
[12] Kunbo Lian, Yun Zhu, Weimin Li, Shengyu Dai *, Changle Chen*. Direct Synthesis of Thermoplastic Polyolefin Elastomers from Nickel-Catalyzed Ethylene Polymerization. Macromolecules 2017, 50, 6074-6080. Monthly most read article in 2017/08 and 2017/09.
[11] Lihua Guo, Chen Zou, Shengyu Dai*, Changle Chen* Direct Synthesis of Branched Carboxylic Acid Functionalized Poly(1-octene) by α-Diimine Palladium Catalysts. Polymers, 2017, 9, 122. Special Issue: Metal Complexes-Mediated Catalysis in Polymerization.
[10] Shengyu Dai, Changle Chen*. Direct Synthesis of Functionalized High-Molecular-Weight Polyethylene from the Copolymerization of Ethylene with Polar Monomers. Angew. Chem. Int. Ed., 2016, 55, 13281-13285. (Highlighted in Synfacts 2016, 12, 1252; Chin. J. Org. Chem. 2016, 36, 3005), ESI Highly Cited Paper.
[9] Shengyu Dai, Shixin Zhou, Wen Zhang, Changle Chen*. Systematic Investigations of Ligand Steric Effects on α-Diimine Palladium Catalyzed Olefin Polymerization and Copolymerization with Methyl Acrylate. Macromolecules 2016, 49, 8855-8862. Monthly most read article in 2016/12 and 2017/01. ESI Highly Cited Paper.
[8] Shengyu Dai, Xuelin Sui, Changle Chen*. Synthesis of High Molecular Weight Polyethylene Using Iminopyridyl Nickel Catalysts. Chem. Commun. 2016, 52, 9113-9116. Special Issue: 2016 Emerging Investigators.
[7] Shengyu Dai, Xuelin Sui, Changle Chen*. Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate. Angew. Chem. Int. Ed., 2015, 54, 9948-9953. (Highlighted in New Chemical Materials 2015, 11, 245.) ESI Highly Cited Paper.
[6] Xuelin Sui, Shengyu Dai, Changle Chen*. Ethylene Polymerization and Copolymerization with Polar Monomers by Cationic Phosphine Phosphonic Amide Palladium Complexes. ACS Catal., 2015, 5, 5932-5937. IF: 12.221, CT: 102. 中科院一区
[5] Lihua Guo, Shengyu Dai, Xuelin Sui, Changle Chen*. Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization. ACS Catal. 2016, 6, 428-441. Monthly most read article in 2016/01 and 02. ESI Highly Cited Paper and ESI Hot Paper.
[4] Chen Zou, Shengyu Dai, Changle Chen*. Ethylene Polymerization and Copolymerization using Nickel 2-Iminopyridine-N-oxide Catalysts: Modulation of Polymer Molecular Weights and Molecular-weight Distributions. Macromolecules 2018, 51, 49–56. ESI Highly Cited Paper.
[3] Xiaohui Hu, Shengyu Dai, Changle Chen*. Ethylene Polymerization by Salicylaldimine Nickel(II) Complexes Containing Dibenzhydryl Moiety. Dalton Trans. 2016, 45, 1496-1503.
[2] Lihua Guo, Shengyu Dai, Changle Chen*. Investigations of the Ligand Electronic Effects on α-diimine Nickel(II) Catalyzed Ethylene Polymerization. Polymers 2016, 8, 37.
[1] Yan-Jun Ding, Yan Li,* Shengyu Dai, Quan Lan and Xi-Sheng Wang* Pd(ii)-catalyzed, co ntrollable C–H mono-/diarylation of aryl tetrazoles: concise synthesis of Losartan. Org. Biomo l. Chem., 2015, 13, 3198–3201.
· 会议展示
· [1] Shengyu Dai, Changle Chen*. Highly Robust Pd(II) α–diimine Catalysts for Olefin (co)Polymerization. APO2015 & WPOC2015, Tokyo Metropolitan University, Japan，Poster.
· [2] 代胜瑜，陈昶乐*。大位阻二亚胺钯催化剂在乙烯聚合以及共聚反应中的应用，2015年全国高分子化学学术报告会，江苏苏州苏州大学, 墙报。(优秀墙报奖)
· [3] Shengyu Dai Highly Robust Pd(II) α–diimine Catalysts for Olefin (co)Polymerization. 253rd ACS National Meeting, 2017, San Francisco, USA, Oral Speaker.
· [4] 代胜瑜* 大位阻柔性取代基在配位聚合中的应用, 2019年全国高分子化学学术报告会，陕西西安西北工业大学, 墙报。
· [5] 代胜瑜* 柔性环烷基取代基在配位聚合中的应用, 2019年全国第十六届有机合成化学学术研讨会，河南开封河南大学, 口头报告。
· [6] 代胜瑜* 生物质功能化聚乙烯热塑性弹性体的合成, 2019年全国应用化学年会，新疆乌鲁木齐新疆大学，邀请报告。
· [7] Shengyu Dai* Application of Coordination Polymerization in the Synthesis of New Polyolefin Materials. APO2019 & WPOC2019, Higashi-Hiroshima, Hiroshima University, Japan, Invited Speaker.
· [8] 代胜瑜* 高插入比极性功能化超支化聚乙烯的制备, 2020年全国高分子材料科学与工程研讨会，海南省海口市海南大学, 口头报告。
· [9] Shengyu Dai*, Shuaikang Li, You Ge. Application of Coordination Polymerization in the Synthesis of High-end Polyolefin Materials. 2021 IAAM Young Scientist Medal Lecture, Advanced Materials Lecture Series. Gammalkilsvägen 18, Ulrika 59053, Sweden. Webinar, Invited Speaker.
· [10] Shengyu Dai* Precise Synthesis of High Performance Polyolefin Materials from Only Ethylene Feedstock. ACS Spring 2021, Live Speaker Presentation.
· [11] 代胜瑜* 后过渡金属催化剂催化乙烯聚合制备高性能能聚烯烃材料，2021年第一届西华化学与生物医药论坛，四川省成都市西华大学，邀请报告。
· [12] 代胜瑜* 后过渡金属催化剂催化乙烯聚合制备高性能能聚烯烃材料，2021年第三届中国化学快报有机化学青年化学家论坛，西藏林芝，大会报告。
· [13] 代胜瑜* 新型后过渡金属有机催化剂在烯烃聚合及共聚中的应用，中国化学会2021年中西部地区无机化学化工学术研讨会，甘肃兰州兰州大学，口头报告。
· [14] Shengyu Dai* Precise Synthesis of High Performance Polyolefin Materials by Chain Walking Strategy. 2021 Vebleo Fellow in the webinar on Materials Science, Engineering and Technology, Keynote Talk.
· [15] Shengyu Dai* Application of Coordination Polymerization in the Synthesis of High-end Polyolefin Materials. Asian Polyolefin Workshop 2021, Thailand, Mahidol University Invited Speaker.
· [16] Shengyu Dai* Facile synthesis of hyperbranched ethylene oligomers and ethylene-MA co-oligomers. ACS Spring 2022, Live Speaker Presentation.
· [17] 代胜瑜* 超支化乙烯齐聚物和乙烯-MA共齐聚物的高效合成，2023年中国化学会第六届西南地区高分子及复合材料学术研讨会，重庆永川，口头报告。
专利：
【1】陈昶乐，代胜瑜，隋学林，大位阻二亚胺钯催化剂及其配体，制备方法和用途。中国专利申请号 CN201510358285.0 申请日：2015年6月25日。授权日：2017年2月3日. 专利授权号：CN105152970B. 专利号：ZL201510358285.0
【2】代胜瑜，李帅康，大位阻柔性二亚胺配体, 基于其的二亚胺镍和钯配合物及其催化有应用。中国专利申请号 CN201910701033.1 申请日：2019年10月11日。专利公开号CN110317149A。专利号：ZL201910701033.1授权日：2022年7月4日.
【3】代胜瑜，李帅康，吡啶亚胺配体，基于其的吡啶亚胺钯配合物及其催化应用。中国专利申请号 CN202010056006.6 申请日：2020年6月5日。专利公开号CN110317149A。
【4】陈昶乐，代胜瑜，二亚胺钯配合物及其配体，制备方法和应用。中国专利申请号 CN 202010103323.9 申请日：2020年6月5日。专利号：ZL202010103323.9. 授权日：2022年12月14日。
【5】陈昶乐，代胜瑜，后过渡金属催化剂催化烯烃均相聚合的气相聚合法。中国专利申请号 CN202010406124.5 申请日：2020年7月14日。专利号：ZL202010406124.5. 授权日：2022年10月01日。
【6】代胜瑜，葛优，一种吡啶亚胺配体、基于该配体的吡啶亚胺镍钯配合物及其在催化乙烯聚合反应中的应用。中国专利申请号 CN202110952504.3 申请日：2021年8月19日。专利号：ZL202110952504.3. 授权日：2023年10月17日。
【7】陈昶乐，隋学林, 代胜瑜，不对称二亚胺钯催化剂及其配体、制备方法和用途, 中国专利申请号 CN201610424926.2 申请日：2016年6月13日。专利号ZL201610424926.2授权日：2018年5月01日。
【8】代胜瑜，陆宙 双空间位阻效应的二亚胺配体及制备方法、高热稳定性二亚胺镍配合物及其制备方法和应用, 中国专利申请号 CN 202111520647.3 申请日：2021年11月15日。
【9】代胜瑜，范慧君 含有柔性环烷基取代基的α-二亚胺配体、基于其的配合物及其催化应用 中国专利申请号 CN 202310255457.6 申请日：2023年3月16日。