化学与材料科学学院

化学与材料科学学院

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崔鹏

作者: 崔鹏     发布时间:2020-06-02 点击数:

崔鹏  (Dr. Peng Cui)

Emailpcui@ahnu.edu.cn

Office:Liqin Building 1139

Lab:Liqin Building 1130,1131,1132 

ORCID: 0000-0003-4011-4144



Biography

2017.7-                  Professor, Anhui Normal University

2015.10-2017.2     Postdoctoral Associate, University of Pennsylvania, USA(with Prof. Neil C. Tomson

2013.10-2015.9     Postdoctoral Fellow, University of Notre Dame, USA(with Prof. Vlad M. Iluc

2011.10-2013.9     Humboldt Postdoctoral Fellow, RWTH-Aachen University, Germany(with Prof. Jun Okuda

2005.09-2011.1     Ph.D., Shanghai Institute of Organic Chemistry, CAS, China(with Prof. Yaofeng Chen

2001.09-2005.8     B.S., Sichuan University, China(with Prof. Meiming Luo



Research

General Description

    杂核金属配合物对于N2, H2, O2等重要小分子的活化转化具有举足轻重的作用。生物体系中固氮酶的FeMo辅因子,光系统中放氧复合物的活性中心Mn4O5Ca,以及[NiFe]氢化酶,都含有两种性质不同的金属离子。在杂金属体系中,由于金属中心性质的差异,对底物进行活化时的模式和作用是不同的:1)通过金属间相互作用调控不同金属中心的电性;2)不同的金属中心对底物进行协同活化;这些传统的单金属以及同核双金属体系中是难以实现的。

    和传统单金属中心的反应模式不同:1)金属-金属键中σπδ键的电子具有丰富的反应性质;2)双金属的协同作用能够调节底物活化过程中的选择性和反应速率。合成表征结构新颖的含有金属-金属键的配合物,研究其与多种底物的当量或催化反应,对于揭示金属-金属键的反应性有重要的意义。


Current Interests

  1. Heterobimetallic Rare-earth and transition metal complexes for small molecule activation & catalysis.

  2. Metal-Metal bond chemistry involving Rare-earth metals. 


Group

Current Group Members

1F44F



Group Photos





Scientific Contributions

Publications at AHNU

25. "Three-Coordinate Pd(0) with Rare-earth Metalloligands: Synergetic CO Activation and Double P-C Bond Cleavage-Formation Reactions" Peng Cui*, Changjiang Wu, Jun Du, Gen Luo*, Zeming Huang, Shuangliu Zhou, Inorg. Chem., 2021, Accepted.



24. "P-C Bond Cleavage Induced Ni(II) Complexes Bearing Rare-earth Metal-Based Metalloligand and Reactivities Toward Isonitrile, Nitrile and Epoxide" Peng Cui*, Xia Huang, Jun Du, Zeming Huang, Inorg. Chem., 2021, 60, 3249-3258.



23. "Heterobimetallic Pd(0) Complexes with Pd→Ln (Ln = Sc, Y, Yb, Lu) Dative Bonds: Rare-earth Metal Dominated Frustrated Lewis pair-like Reactivity." Jun Du, Yanan Zhang, Zeming Huang, Shuangliu Zhou*, Huayi Fang*, Peng Cui*, Dalton Trans., 2020, 49, 12311–12318.


 

22. "Heterobimetallic Scandium-Group 10 Metal Complexes with LM→Sc (LM = Ni, Pd, Pt) Dative Bond." Peng Cui*, Chunyan Xiong, Jun Du, Zeming Huang, Sijun Xie, Hua Wang, Shuangliu Zhou, Huayi Fang*, Shaowu Wang*, Dalton Trans., 2020, 49, 124–130.



21. "A Scandium Metalloligand Based Heterobimetallic Pd-Sc Complex: Electronic Tuning Through a Very Short Pd→Sc Dative Bond." Jun Du, Zeming Huang, Yanan Zhang, Shaowu Wang, Shuangliu Zhou*, Huayi Fang*, Peng Cui*, Chem. Eur. J. 2019, 25, 10149–10155.





Publications Before AHNU

20. "Oxidation Reactions of a Nucleophilic Palladium Carbene: Mono and Bi-radical Carbenes." Peng Cui, Melissa R. Hoffbauer, Mariya Vyushkova, Vlad M. Iluc*, Dalton Trans., 2019, 48, 9663-9668.

19. “Ring Size Modulated Reactivity of Putative Dicobalt Bridging Nitrides: C–H Activation vs. Phosphinimide Formation.” Peng Cui, Qiuran Wang, Sam P. McCollom, Brian C. Manor, Patrick J. Carrol, Neil C. Tomson*, Angew. Chem. Int. Ed. 2017, 56, 15979–15983.

18. “Molecular Magnesium Hydrides Supported by an Anionic Triazacyclononane-Type Ligand.” S. Schnitzler, P. Cui, T. P. Spaniol and J. Okuda*, Dalton Trans., 2017, 46, 1761-1765.

17. “Boratabenzene Rare-earth Metal Complexes.” Peng Cui, Yaofeng Chen*, Coord. Chem. Rev. 2016, 314, 2-13.

16. “C-H Activation of Ethers by Pyridine Tethered PCsp3P-type Iridium Complexes” Peng Cui, Dominic C. Babbini, Vlad M. Iluc*, Dalton Trans., 2016, 45, 10007-10016.

15. “Heterobimetallic Pd-K Carbene Complexes via One-Electron Reductions of Palladium Radical Carbenes.” Peng Cui, Melissa R. Hoffbauer, Mariya Vyushkova, Vlad M. Iluc*, Chem. Sci., 2016, 4444-4452.

14. “Redox-Induced Umpolung of Transition Metal Carbenes.” Peng Cui, Vlad M. Iluc*, Chem. Sci., 2015, 6, 7343-7354.

13. “Frustrated Lewis Pair-Like Reactions of Nucleophilic Palladium Carbenes with B(C6F5)3.”Peng Cui, Cezar C. Comanescu, Vlad M. Iluc*, Chem. Commun., 2015, 51. 6206-6209.

12. “An Ion Pair Scandium Hydride Supported by a Dianionic (NNNN)-Type Macrocycle Ligand.”Peng Cui, Thomas P. Spaniol, Laurent Maron*, Jun Okuda*, Chem. Commun., 2014, 50, 424-426.

11. “Dehydrogenation of Amine–Borane Me2NH·BH3 Catalyzed by A Lanthanum Hydride Complex.” Peng Cui, Thomas P. Spaniol, Laurent Maron*, Jun Okuda*, Chem. Eur. J. 2013, 19, 13437-13444.

10. “Heterometallic Potassium Rare–Earth Metal Allyl and Hydrido Complexes Stabilized by A Dianionic (NNNN) Macrocyclic Ancillary Ligand.” Peng Cui, Thomas P. Spaniol, Jun Okuda*, Organometallics,2013, 32, 1176-1182.

9. “Synthesis and Catalytic Activity of Amido-Boratabenzene Complexes of Rare-Earth Metals and Zirconium and Chromium.” Xiufang Wang, Weijie Peng, Peng Cui, Xuebing Leng, Wei Xia, Yaofeng Chen*, Organometallics, 2013, 32, 6166-6169.

8. “Boratatrozircenes: cycloheptatrienyl zirconium boratabenzene sandwich complexes–evaluation of potential η6η5 hapticity interconversions.” Andreas Gl?ckner, Peng Cui, Yaofeng Chen, Constantin G. Daniliuc, Peter G. Jones and Matthias Tamm*, New. J. Chem. 2012, 36, 1392-1398.

7. “Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali–Metal Salts and the Generation of Heterometallic Ytterbium–Alkali–Metal Boratabenzene Complexes.”Peng Cui, Yaofeng Chen*, Guangyu Li and Wei Xia, Organometallics, 2011, 30, 2012-2017.

6. “Synthesis, and Structure Characterization of Solvent-free Divalent Ytterbium Bis(boratabenzene) and (Cyclopentadienyl)(Boratabenzene) Complexes.” Peng Cui, Yaofeng Chen*, Qiang Zhang, Guangyu Li, Wei Xia, J. Organomet. Chem., 2010, 695, 2713-2719.

5. “Neodymium(ш) phosphinidene complexes supported by pentamethylcyclopentadienyl and hydrotris(pyrazolyl)borate ligands. Peng Cui, Yaofeng Chen*, Maxim V. Borzov, Dalton Trans., 2010, 39, 6886-6890.

4. “An unprecedented lanthanide phosphinidene halide: synthesis, structure and reactivity.” Peng Cui, Yaofeng Chen*, Xin Xu and Jie Sun, Chem. Commun., 2008, 5547-5549.

3. “An ansa-Heteroborabenzene Divalent Lanthanide Amide Through C-H Bond Cleavage.” Peng Cui, Yaofeng Chen*, Guangyu Li and Wei Xia, Angew. Chem. Int. Ed. 2008, 47, 9944-9947.

2. “Divalent Ytterbium Boratabenzene Complex (C5H5BNPh2)2Yb(THF)2: Synthesis, Structure, and Solvent-Mediated Redox Transformation.” Peng Cui, Yaofeng Chen*, Guoping Wang, Guangyu Li and Wei Xia, Organometallics, 2008, 27, 4013-4016.

1. “Boratabenzene Derivatives of Divalent Samarium: Synthesis, Structures and Catalytic Reactivities of (C5H5BXPh2)2Sm(THF)2 (X = N, P).” Peng Cui, Yaofeng Chen*, Xiaohua Zeng, Jie Sun, Guangyu Li and Wei Xia, Orgnometallics, 2007, 26, 6519-6521.


Publications in Books

2. “Scandium ComplexesPeng Cui, Invited Chapter in “Comprehensive Coordiantion Chemistry III”, Elsevier, 2020. Accepted.

1. “Pincer-Carbenoid Complexes with Late-transition Metals: Synthesis, Electronic Structure and Reactivity.Peng Cui, Vlad M. Iluc, Chapter 17 in “Pincer Compounds---Chemistry and Applications”, Elsevier, 2018.



Invites Talks & Lectures

1. “基于电子可调控的大环配体双铁、双钴氮化物化学,口头报告,第16届江淮有机化学论坛,苏州大学,201810

2.  “基于LM-Ln配键的稀土-后过渡金属杂核配合物,邀请报告,第10届全国无机化学学术会议,山东大学,20198

3. “基于LM-Ln配键的稀土-后过渡金属杂核配合物,邀请报告,第6届全国稀土金属有机化学讨论会,苏州大学,201910

 


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