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功能性分子固体省部共建教育部重点实验室

2013-2017年代表性科研成果

 
 

一、发表性论文

     近5年共发表SCI论文676篇,其中4.0以上论文298篇,在自然指数期刊发表论文数49篇。

  1. Xiancui Zhu, Yang Li, Yun Wei, Shaowu Wang*, Shuangliu Zhou, and Lijun Zhang, Reactivity of Imino-Functionalized Indoles with Rare-Earth-Metal Amides: Unexpected Substituent Effects on CH Activation Pathways and Assembly of Rare-Earth-Metal Complexes.Organometallics, 2016, 35, 18381846.
  2. Xiaoxia Gu, XiancuiZhu,* Yun Wei, Shaowu Wang*,  Shuangliu Zhou, Guangchao Zhang, and Xiaolong Mu, “CNC-Pincer Rare-Earth Metal Amido Complexes with a Diarylamido Linked Biscarbene Ligand: Synthesis, Characterization and Catalytic Activity, Organometallics,2014, 33 (9), 2372–2379.
  3. Guangchao Zhang, Yun Wei, Liping Guo, Xiancui Zhu, Shaowu Wang*,  Shuangliu Zhou, and Xiaolong Mu, Dinuclear Rare-Earth Metal Alkyl Complexes Supported by Indolyl Ligands in m-h2:h1:h1 Hapticities and their High Catalytic Activity for Isoprene 1,4-cis-Polymerization.Chem. Eur. J.2015, 21(6), 2519-2526.
  4. Liping Guo, Xiancui Zhu, Guangchao Zhang, Yun Wei, Lixin Ning, ShuangliuZhou,* Zhijun, Feng, Shaowu Wang*, Xiaolong Mu, Jun Chen, and Yuzhe Jiang, “Synthesis, Characterization of Organo Rare-Earth Metal Monoalkyl Complexes Supported by Carbon σ-Bonded Indolyl Ligands: High Specific Isoprene 1,4-cis Polymerization Catalysts,” Inorg. Chem.2015, 54(12), 5725-5731.
  5. Shaoyin Wang, Zhuo Chai, Yun Wei, Xiancui Zhu, Shuangliu Zhou, and Shaowu Wang*, Lewis Acid Catalyzed Cascade Reaction to Carbazoles and Naphthalenes via Dehydrative [3 + 3]-Annulation. Org. Lett.2014, 16, 3592-3595.
  6. Qingbing Yuan, Shuangliu Zhou*, Xiancui Zhu, Yun Wei, Shaowu Wang, Xiaolong Mu, Fangshi Yao, Guangchao Zhang and Zheng Chen,Heterometallic rare-earth metal complexes with imino-functionalized 8-hydroxyquinolyl ligands: synthesis, characterization and catalytic activity towards hydrophosphinylation of trans-β-nitroalkene.New J. Chem., 2015, 39, 7626-7632.
  7. ShuangliuZhou,*Zhiyong Yang, Xu Chen, Yimei Li, Lijun Zhang, Hong Fang, Wei Wang, Xiancui Zhu, and Shaowu Wang*, “Copper-Catalyzed Electrophilic Amination of Organoaluminum Nucleophiles with O-Benzoyl Hydroxylamines” J. Org. Chem.2015, 80, 6323-6328.
  8. Liping Guo, Xiancui Zhu, ShuangliuZhou,*Xiaolong Mu, Yun Wei, Shaowu Wang*,Zhijun Feng, Guangchao Zhang, and Baojia Deng, Rare-Earth Alkyl Complexes Supported by Formamidinate Ligands: Synthesis, Structure, and Catalytic Activity for Isoprene Polymerization. Dalton Trans. 2014, 43 (18), 6842 – 6847.
  9. Wenhai Wang, Long Kuai, Wei Cao, Marko Huttula, Sami Ollikkala, TaruAhopelto, Ari-PekkaHonkanen, Simo Huotari, Mengkang Yu, and BaoyouGeng*, Mass-Production of Mesoporous MnCo2O4 Spinels with Manganese(IV)- and Cobalt(II)-Rich Surfaces for Superior Bifunctional Oxygen Electrocatalysis. Angew. Chem. Int. Ed. 2017, 56, 14977-14981.  
  10. Li, Min, Du, Haoran, Kuai, Long, Huang, Kuangfu, Xia, Yuanyuan, Geng, Baoyou*, Scalable Dry Production Process of a Superior 3D Net-Like Carbon-Based Iron Oxide Anode Material for Lithium-Ion Batteries. Angew. Chem. Int. Ed. 2017,56,41, 1249-12653. 
  11. Kuai, Long, Geng, Jing, Chen Changyu, Kan Erjie, Liu Yadong, Wang Qing and BaoyouGeng*,  A Reliable Aerosol-Spray-Assisted Approach to Produce and Optimize Amorphous Metal Oxide Catalysts for Electrochemical Water Splitting, Angew. Chem. Int. Ed. 2014, 53, 7547 –7551.
  12. Yadong Liu, Zhen Fang, Long Kuai and BaoyouGeng*,  One-pot facile synthesis of reusable tremella-like M1@M2@M1(OH)2 (M1 = Co, Ni, M2 = Pt/Pd, Pt, Pd and Au) three layers core–shell nanostructures as highly efficient catalysts, Nanoscale, 2014,6, 9791-9797.
  13. Zhao Yanyan, Kuai Long, Liu Yanguo, Wang Pengpeng, ArandiyanHamidreza, Cao Sufeng, Zhang Jie, Li Fengyun, Wang Qing, GengBaoyou &Hongyu Sun, Well-Constructed Single-Layer Molybdenum Disulfide Nanorose Cross-Linked by Three Dimensional-Reduced Graphene Oxide Network for Superior Water Splitting and Lithium Storage Property, Sci. Rep. 2015,5.
  14. Kan Erjie, Kuai Long, Wang Wenhai, GengBaoyou, Delivery of Highly Active Noble-Metal Nanoparticles into Microspherical Supports by an Aerosol-Spray Method. Chem. Eur. J., 2015, 21, 13291-13296.
  15. Wenzheng Li, Long Kuai, Qing Qin and BaoyouGeng*. Ag–Au bimetallic nanostructures: co-reduction synthesis and their component-dependent performance for enzyme-free H2O2 sensing. J. Mater. Chem. A, 2013, 1, 7111–7117.
  16. Wang, Qing, Geng, Jing, Yuan, Chao, Kuai, Long and Geng, Baoyou*, Mesoporous spherical Li4Ti5O12/TiO2 composites as an excellent anode material for lithium-ion batteries. Electrochim. Acta, 2016,212, 41-46.  
  17. ZnO nanorods/ZnSeheteronanostructure arrays with a tunable microstructure of ZnSe shell for visible light photocatalysis.J. Mater. Chem. A, 2014, 2, 17502-17510.
  18. Zhuo Chai,* You-Min Zhu, Pei-Jun Yang, Shaoyin Wang, Shaowu Wang,* Zhen Liu, Gaosheng Yang, “Copper(I)-Catalyzed Kinetic Resolution of N-Sulfonylaziridines with Indoles: Efficient Construction of Pyrroloindolines”, J. Am. Chem. Soc. 2015, 137, 10088–10091.
  19. Zhuo Chai,* Pei-Jun Yang, Hu Zhang, Shaowu Wang, Gaosheng Yang, “Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis of N-Tosylaziridines”, Angew. Chem. Int. Ed. 2017, 56, 650–654.
  20. Zhuo Chai,* Jia-Nan Chen, Zhen Liu, Xue-Fei Li, Pei-Jun Yang, Ji-Ping Hu, Gaosheng Yang, “[3+2]-Annulations of N-alkyl-3-substituted indoles with quinone monoketalscatalysed by Brnsted acids”, Org. Biomol. Chem. 2016, 14, 1024–1030.
  21. Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu, GaoshengYang,* “A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination”, Chem. Commun. 2014, 50, 177–179.
  22. ZhuoChai,* Biao Wang, Jia-Nan Chen, Gaosheng Yang, “Arylation of Azlactones using Diaryliodonium Bromides and Silver Carbonate: Facile Access to alpha-Tetrasubstituted Amino Acid Derivatives”, Adv. Synth. Catal. 2014,356, 2714–2718.
  23. Shaoyin Wang, Xiancui Zhu, ZhuoChai,* and Shaowu Wang,* “Synthesis of polysubstituted pyrroles via [3+2]-annulation of aziridines and beta-nitroalkenes under aerobic conditions”, Org. Biomol. Chem. 2014, 12, 1351–1356.
  24. Gaosheng Yang,*Yongxian Sun, Yue Shen, Zhuo Chai,* Shuangliu Zhou, Jiang Chu, Jun Chai, “cis-2,3-Disubstituted Cyclopropane 1,1-Diesters in [3+2] Annulations with Aldehydes: Highly Diastereoselective Construction of Densely Substituted Tetrahydrofurans”, J. Org. Chem. 2013, 78, 5393–5400.
  25. Sheng, W.; Zheng, Y.; Wu, Q.; Wu, Y.; Yu, C.; Jiao, L.* Hao, E.; Wang, J.-Y.* Pei, J. Synthesis, Properties, and Semiconducting Characteristics of BF2 Complexes of beta,beta-Bisphenanthrene-Fused Azadipyrromethenes. Org. Lett., 2017, 19, 2893-2896.
  26. Chen, N.; Zhang, W.; Chen, S.; Wu, Q.; Yu, C.; Wei, Y.; Xu, Y.; Hao, E.; Jiao, L.* Sterically Protected N2O-Type Benzopyrromethene Boron Complexes from Boronic Acids with Intense Red/Near-Infrared Fluorescence. Org. Lett.,  2017, 19, 2026-2029.
  27. Zhang, W.; Sheng, W.; Yu, C.; Wei, Y.; Wang, H.; Hao, E.;* Jiao, L.* One-pot synthesis and properties of well-defined butadiynylene-BODIPY oligomers. Chem. Commun., 2017, 5318-5321.
  28. Li, J.; Zhang, Q.; Yin, J.; Yu, C.; Hao, E.; Wei, Y.; Mu, X.; Jiao, L.* Metal-Free and Versatile Synthetic Routes to Natural and Synthetic Prodiginines from Boron Dipyrrin. Org. Lett., 2016, 18, 5696-5699.
  29. Feng, Z.; Jiao, L.*;Feng, Y.; Yu, C.; Chen, N.; Wei, Y.; Mu, X.; Hao, E.* Regioselective and Stepwise Syntheses of Functionalized BODIPY Dyes through Palladium-Catalyzed Cross-Coupling Reactions and Direct C-H Arylations. J. Org. Chem.,2016, 81, 6281-6291.
  30. Zhou, X.;Wu, Q.; Yu, Y.; Yu, C.; Hao, E.; Wei, Y.; Mu, X.; Jiao, L.* Metal-Free Direct alpha-Selective Arylation of Boron Dipyrromethenes via Base-Mediated C-H Functionalization. Org. Lett., 2016, 18, 736-739.
  31. Zhou, X.; Yu, C.; Feng, Z.; Yu, Y.; Wang, J.; Hao, E.; Wei, Y.; Mu, X.; Jiao, L.* Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride. Org. Lett.,  2015, 17, 4632-4635.
  32. 8. Yu, C.; Jiao, L.*; Li, T.; Wu, Q.; Miao, W.; Wang, J.; Wei, Y.; Mu, X.; Hao, E.* Fusion and Planarization of bisBODIPY: a New Family of Photostable Near Infrared Dyes. Chem. Commun.,  2015, 51, 16852-16855.
  33. 9.Wu, Y.; Cheng, C.; Jiao, L.*; Yu, C.; Wang, S.;* Wei, Y.; Mu, X.; Hao, E.* β-Thiophene-Fused BF2-Azadipyrromethenes as Near-Infrared Dyes. Org. Lett., 2014, 16, 748-751.
  34. Yan Zhao, Yucheng Huang (cofirst author), Hui Zhu, Qingqing Zhu, Yunsheng Xia*, Three-in-one: Sensing, self-assembly and c ascade  catalysis of cyclodextrin modified gold nanoparticles, J.Am.Chem.Soc., 2016, 138, 16645-16654.
  35. Junyong Sun, Han Mei, Sufan Wang, and Feng Gao*.Two-Photon Semiconducting Polymer Dots with Dual-Emission for Ratiometric Fluorescent Sensing and Bioimaging of Tyrosinase Activity. Anal. Chem., 2016, 88, 7372-7377.
  36. Mei Zhao, Yue Gao, Junyong Sun, and Feng Gao*.Mediatorless Glucose Biosensor and Direct Electron Transfer Type Glucose/Air Biofuel Cell Enabled with Carbon Nanodots. Anal. Chem., 2015, 87, 2615-2622.
  37. HuideChen,Yunsheng Xia*, Compact hybrid (gold nanodendrite-quantum dots) assembly: Plasmon enhanced fluorescence-based platform for small molecule sensing in solution, Analytical Chemistry, 2014, 86, 11062-11069.
  38. LinlinLu,Yunsheng Xia*, Enzymatic reaction modulated gold nanorod end-to-end self-assembly for ultrahigh sensitively colorimetric sensing of cholinesterase and o rganophosphate pesticides  in human blood, Analytical Chemistry, 2015, 87, 8584-8591.
  39.  Wang, Guangfeng*, Xu, Gang, Zhu, Yanhong, Zhang, Xiaojun*, A "turn-on'' carbon nanotube-Ag nanoclusters fluorescent sensor for sensitive and selective detection of Hg2+ with cyclic amplification of exonuclease III activity, Chem. Commun.,2014, 50(6): 747-750.
  40. Yongxin Li,* Qingqing Wu, Shoufeng Jiao, Chaodi Xu, and Lun Wang,Single Pt Nanowire Electrode: Preparation, Electrochemistry, and Electrocatalysis,Anal. Chem. 2013, 85, 41354140.
  41. Yaoyao Zhang, Shen Xu, Xiaoqing Xiao, Yong Liu, Yuanyuan Qian and Yongxin Li*,Single gold nanowire electrodes and single Pt@Au nanowire electrodes: electrochemistry and applications,Chem. Commun.,2017, 53, 2850—2853.
 
 

二、科技奖励

序号

编号

项目名称

奖励类型

完成人名单

1

2015-2-R1

DNA传感器的设计、制备及应用

安徽省科学技术奖二等奖

张玉忠、张克营、汪杰

2

2016-109

电化学生物传感界面的构建、性能研究及应用

教育部自然科学奖二等奖

王广凤、阚显文、王银玲、方宾

3

2016-2-D1

电化学生物传感界面的构建、性能研究及应用

安徽省科学技术奖二等奖

王广凤、阚显文、王银玲、方宾

4

2017-3-R1

廉价过渡金属催化的有机反应研究及其应用

安徽省科学技术奖 三等奖

商永嘉、张武、何心伟

5

2015jxms010

教学名师

省级教学名师

杨高升

6

2013cgj029

以国家级“质量工程”为航标,构筑高师化学专业优质教育教学平台

省级教学成果奖一等奖

朱昌青、王绍武、王伦、魏先文、江家发、顾家山、高峰

7

2015cgj045

对接与重构:着眼“卓越化学教师”的师范生实践教育体系的理论构建与实践

省级教学成果奖二等奖

高峰、孙影、张武、阚显文、朱昌青

 

 
 

三、出版著作

序号

专著名称

出版年度

作者

1

化学实验(上、中、下册)

2015年

方宾、王伦、高峰、张武、周映华、孙礼林、张明翠、唐业仓、肖艳玲、罗时忠、王正华、盛恩宏

2

化学化工文献信息检索 第2版

2016年

李一梅、罗时忠、王银玲、王伟智

 

 
 

四、重点实验室建设期间获得国家专利情况

    2013-2017年共申请国家专利408项,授权发明专利150项。

 

 

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电子邮箱:ssj1234@mail.ahnu.edu.cn  电话:0553-3937135 传真:0553-3869302